Five Key Publications

1.        On the stability enhancement of cuprous oxide water splitting photocathodes by low temperature steam annealing. Azevedo, J., Steier, L., Dias, P., Stefik, M., Sousa, C. T., Araújo, J. P., Mendes, A., Graetzel, M. & Tilley, S. D. Energy Environ. Sci. 7, 4044–4052 (2014).

2.        Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts. Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J. & Gratzel, M. Science 345, 1593–1596 (2014).

3.        Light-Induced Water Splitting with Hematite: Improved Nanostructure and Iridium Oxide Catalysis. Tilley, S. D., Cornuz, M., Sivula, K. & Grätzel, M. Angew. Chemie Int. Ed. 49, 6405–6408 (2010).

4.        Ruthenium Oxide Hydrogen Evolution Catalysis on Composite Cuprous Oxide Water Splitting Photocathodes. Tilley, S. D., Schreier, M., Azevedo, J., Stefik, M. & Grätzel, M. Adv. Funct. Mater. 24, 303–311 (2014).

5.        Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst. Morales-Guio, C. G., Tilley, S. D., Vrubel, H., Grätzel, M. & Hu, X. Nat. Commun. 5, 3059 (2014).

       

Publications

1.        Solution Transformation of Cu2O into CuInS2 for Solar Water Splitting. Luo, J., Tilley, S. D., Steier, L., Schreier, M., Mayer, M. T., Fan, H. J. & Graetzel, M. Nano Lett. (2015). doi:10.1021/nl504746b

2.        Photoelectrochemical Hydrogen Production in Alkaline Solutions Using Cu2O Coated with Earth-Abundant Hydrogen Evolution Catalysts. Morales-Guio, C. G., Liardet, L., Mayer, M. T., Tilley, S. D. & Grätzel, M. Angew. Chemie Int. Ed. 664–667 (2015). doi:10.1002/anie.201410569

3.        Efficient and selective carbon dioxide reduction on low cost protected Cu2O photocathodes using a molecular catalyst. Schreier, M., Gao, P., Mayer, M. T., Luo, J., Moehl, T., Nazeeruddin, M. K., Tilley, S. D. & Grätzel, M. Energy Environ. Sci. (2015). doi:10.1039/c4ee03454f

4.        On the stability enhancement of cuprous oxide water splitting photocathodes by low temperature steam annealing. Azevedo, J., Steier, L., Dias, P., Stefik, M., Sousa, C. T., Araújo, J. P., Mendes, A., Graetzel, M. & Tilley, S. D. Energy Environ. Sci. 7, 4044–4052 (2014).

5.        A Bismuth Vanadate–Cuprous Oxide Tandem Cell for Overall Solar Water Splitting. Bornoz, P., Abdi, F. F., Tilley, S. D., Dam, B., van de Krol, R., Graetzel, M. & Sivula, K. J. Phys. Chem. C 118, 16959–16966 (2014).

6.        Back electron-hole recombination in hematite photoanodes for water splitting. Le Formal, F., Pendlebury, S. R., Cornuz, M., Tilley, S. D., Grätzel, M. & Durrant, J. R. J. Am. Chem. Soc. 136, 2564–2574 (2014).

7.        Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts. Luo, J., Im, J.-H., Mayer, M. T., Schreier, M., Nazeeruddin, M. K., Park, N.-G., Tilley, S. D., Fan, H. J. & Gratzel, M. Science 345, 1593–1596 (2014).

8.        Hydrogen evolution from a copper(I) oxide photocathode coated with an amorphous molybdenum sulphide catalyst. Morales-Guio, C. G., Tilley, S. D., Vrubel, H., Grätzel, M. & Hu, X. Nat. Commun. 5, 3059 (2014).

9.        Ultrafast charge carrier recombination and trapping in hematite photoanodes under applied bias. Pendlebury, S. R., Wang, X., Le Formal, F., Cornuz, M., Kafizas, A., Tilley, S. D., Grätzel, M. & Durrant, J. R. J. Am. Chem. Soc. 136, 9854–9857 (2014).

10.      Understanding the Role of Underlayers and Overlayers in Thin Film Hematite Photoanodes. Steier, L., Herraiz-cardona, I., Gimenez, S., Fabregat-santiago, F., Bisquert, J., Tilley, S. D. & Grätzel, M. Adv. Funct. Mater. 24, 7681–7688 (2014).

11.      Ruthenium Oxide Hydrogen Evolution Catalysis on Composite Cuprous Oxide Water Splitting Photocathodes. Tilley, S. D., Schreier, M., Azevedo, J., Stefik, M. & Grätzel, M. Adv. Funct. Mater. 24, 303–311 (2014).

12.      Toward a Synthesis of Hirsutellone B by the Concept of Double Cyclization. Reber, K. P., Tilley, S. D., Carson, C. A. & Sorensen, E. J. J. Org. Chem. 78, 9584–9607 (2013).

13.      Optimization and stabilization of electrodeposited Cu2ZnSnS 4 photocathodes for solar water reduction. Rovelli, L., Tilley, S. D. & Sivula, K. ACS Appl. Mater. Interfaces 5, 8018–8024 (2013).

14.      Silicon protected with atomic layer deposited TiO2: durability studies of photocathodic H2 evolution. Seger, B., Tilley, D. S., Pedersen, T., Vesborg, P. C. K., Hansen, O., Graetzel, M. & Chorkendorff, I. RSC Adv. 3, 25902–25907 (2013).

15.      Silicon protected with atomic layer deposited TiO2: conducting versus tunnelling through TiO2. Seger, B., Tilley, S. D., Pedersen, T., Vesborg, P. C. K., Hansen, O., Graetzel, M. & Chorkendorff, I. J. Mater. Chem. A 1, 15089–15094 (2013).

16.      Ultrathin films on copper(I) oxide water splitting photocathodes: a study on performance and stability. Paracchino, A., Mathews, N., Hisatomi, T., Stefik, M., Tilley, S. D. & Grätzel, M. Energy Environ. Sci. 5, 8673 (2012).

17.      Light-Induced Water Splitting with Hematite: Improved Nanostructure and Iridium Oxide Catalysis. Tilley, S. D., Cornuz, M., Sivula, K. & Grätzel, M. Angew. Chemie Int. Ed. 49, 6405–6408 (2010).

18.      Bond formations by intermolecular and intramolecular trappings of acylketenes and their applications in natural product synthesis. Reber, K. P., Tilley, S. D. & Sorensen, E. J. Chem. Soc. Rev. 38, 3022–3034 (2009).

19.      A rapid, asymmetric synthesis of the decahydrofluorene core of the hirsutellones. Tilley, S. D., Reber, K. P. & Sorensen, E. J. Org. Lett. 11, 701–703 (2009).

20.      Proteins: Chemistry and Chemical Reactivity. Tilley, S. D., Joshi, N. S. & Francis, M. B. in Wiley Encycl. Chem. Biol. 1–16 (2008). doi:10.1002/9780470048672.wecb493

21.      Tyrosine-selective protein alkylation using Pi-allylpalladium complexes. Tilley, S. D. & Francis, M. B. J. Am. Chem. Soc. 128, 1080–1081 (2006).