Publications
Publications Prof. Roger Alberto 1985 - 2016
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Publications
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Journal Article
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2025
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The role of $\left[\text{Re}(\eta^6\text{-arene})_2\right]^+$ substituents in electro- and photocatalytic water reduction with $\left[\text{Co}(\text{terpy})_2\right]^{3+}$ catalysts Catalysis Science & Technology, 15(5):1627-1633.
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2024
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Synthesis, Characterization, and Biological Evaluation of Novel [M(η6-arene)2]+ (M = Re, 99mTc) Hosted Terpyridines and Copper Complexes Thereof Inorganic Chemistry, 63(39):18154-18161.
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Direct Anchoring of Molybdenum Sulfide Molecular Catalysts on Antimony Selenide Photocathodes for Solar Hydrogen Production ACS Energy Letters, 9(8):3828-3834.
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Reactivities of Some Unsaturated Hydrocarbons with the Half-Sandwich Complex [Re(η6-C6H6)(NCCH3)3]+ Organometallics, 43(4):557-563.
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Synthesis and Photophysical Evaluation of 3,3’‐Nitrogen Bis‐Substituted $fac$‐[Re(CO)$_3$(Diimine)Br] Complexes Helvetica Chimica Acta, 107(2):e202300239.
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Induced $fac-mer$ rearrangements in {M(CO)$_3$}$^{+}$ complexes (M = Re, $^{99(m)}$Tc) by a PNP ligand Dalton Transactions, 53(4):1434-1438.
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Light-Driven Ring Slippage in [Re(η7-C7H7)(η5-C7H9)]+ and the Inertness of Its Technetium Homologue Inorganic Chemistry, 63(5):2701-2708.
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2023
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From carbonyls to $π$-aromatic arenes: A thirty years journey through organometallic technetium chemistry Journal of Organometallic Chemistry, 1000:122828.
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In vivo and in vitro studies of [M(η$^6$-pseudoerlotinib)$_2$]$^+$ sandwich complexes (M = Re, 99m$_T$$_c$) Dalton Transactions, 52(43):15757-15766.
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Binding Small Molecules to a cis-Dicarbonyl $^{\text{99}}$$Tc^{\text{I}}$-PNP Complex via Metal–Ligand Cooperativity Inorganic Chemistry, 62(27):10727-10735.
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Reactivities of [Re(η6-C6H6)(η6-C10H8)]+ and [Re(η6-C10H8)2]+ with Cyclic, Nonaromatic Polyenes ACS Applied Bio Materials, 42(9):838-845.
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Exploring Rhenium Arene Piano-Stool Chemistry with [Re(η6-C6H6)(NCCH3)3]+: A Powerful Semi-Solvated Precursor Inorganic Chemistry, 62(10):4227-4237.
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2022
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One Electron Changes Everything: Synthesis, Characterization, and Reactivity Studies of [Re(NCCH3)6]3+ Inorganic Chemistry, 61(46):18325-18334.
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High-Yield 99mTc Labeling of Gold Nanoparticles Carrying Atropine and Adrenaline Bioconjugate Chemistry, 33(9):1741-1749.
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Complexes of orotic acid and derivatives with the fac-[M(CO)3]+ (M = Re and 99Tc/99mTc) core as radiopharmaceutical probes. Inorganica Chimica Acta, 539:121037.
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Polar Substituents Enable Efficient Catalysis for a Class of Cobalt Polypyridyl Hydrogen Evolving Catalysts Helvetica Chimica Acta, 105(3):e202100237.
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A Multi-Functional Tool - Cyclopentadienyl Re and 99mTc Complex Synthesis on Highly Functionalised Arenes Journal of Organometallic Chemistry, 962:122281.
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Watching Hydrogens Migrate: Step by Step from [ReI(η6-C6H6)2]+ to [ReIII(η3-C6H9)(η6-C6H6)(NCCH3)2]2+ Inorganic Chemistry, 61(8):3683-3689.
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Naphthalene Exchange in [Re(η6-napht)2]+ with Pharmaceuticals Leads to Highly Functionalized Sandwich Complexes [M(η6-pharm)2]+ (M=Re/99mTc) Chemistry - A European Journal, 28(5):e202103566.
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An isoindoline bridged [M(η6-arene)2]+ (M = Re, 99mTc) ansa-arenophane and its dinuclear macrocycles with axial chirality Dalton Transactions, 51(25):9591-9595.
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2021
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Efficient Alkaline Water Oxidation with a Regenerable Nickel Pseudo-Complex ACS applied materials & interfaces, 13(41):48661-48668.
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The crystal structure of cis-diaqua-bis (N-butyl-N-(pyridin-2-yl)pyridin-2-amine-κ2N,N′)cobalt(II)] dichloride trihydrate, C28H44Cl2N6O5Co Zeitschrift für Kristallographie - New Crystal Structures, 236(5):1065-1068.
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Relativity as a Synthesis Design Principle: A Comparative Study of [3 + 2] Cycloaddition of Technetium(VII) and Rhenium(VII) Trioxo Complexes with Olefins Inorganic Chemistry, 60(15):11090-11097.
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Expanding the Cyclopentadienyl Framework: 99mTc/Re Complexes with Orthogonal Functions for Bioconjugation Bioconjugate Chemistry, 32(7):1393-1398.
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[Re(η6-C6H5-benzimidazole)2]+ and Derivatives as Dye Mimics; Synthesis, UV Absorption Studies and DFT Calculations European Journal of Inorganic Chemistry, 2021(25):2493-2498.
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cis-Locked Ru(II)-DMSO Precursors for the Microwave-Assisted Synthesis of Bis-Heteroleptic Polypyridyl Compounds Inorganic Chemistry, 60(10):7180-7195.
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Exploring the Coordination Chemistry of N2 with Technetium PNP Pincer-Type Complexes Inorganic Chemistry, 60(9):6696-6701.
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Convenient Cyclopentadiene Modifications for Building Versatile (Radio‐)Metal Cyclopentadienyl Frameworks European Journal of Inorganic Chemistry, 2021(16):1611-1614.
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Probing BRD Inhibition Substituent Effects in Bulky Analogues of (+)‐JQ1 Helvetica Chimica Acta, 104(3):e2000214.
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A novel benzoylthiourea derivative with a triazinethione moiety: Synthesis and coordination with the organometallic fac-[Re(CO)3]+ core Inorganica Chimica Acta, 516:120116.
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Organometallic small molecule kinase inhibitors – direct incorporation of Re and 99mTc into Opaganib® Chemical Communications, 57(98):13349-13352.
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Exploring preliminary structural relationships and mitochondrial targeting of fac-[MI(CO)3]-bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re) New Journal of Chemistry, 45(47):22141-22149.
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New approach for the synthesis of water soluble fac-[MI(CO)3]+ bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re) Dalton Transactions, 50(47):17506-17514.
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Excited-state structure of copper phenanthroline-based photosensitizers Physical Chemistry Chemical Physics (PCCP), 23(47):26729-26736.
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2020
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Bioorganometallic Technetium and Rhenium Chemistry: Fundamentals for Applications CHIMIA International Journal for Chemistry, 74(12):953.
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Fully Solvated, Monomeric ReII Complexes: Insights into the Chemistry of [Re(NCCH3)6]2+ Inorganic Chemistry, 59(23):17600-17607.
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CO2 to CO: Photo‐ and electrocatalytic conversion based on Re(I) Bis‐Arene Frameworks: synergisms between catalytic subunits Helvetica Chimica Acta, 103(10):e2000147.
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The “Carbonyl Story” and Beyond; Experiences, Lessons and Implications Chembiochem, 21(19):2743-2749.
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Light‐activated carbon monoxide prodrugs based on bipyridyl dicarbonyl ruthenium(II) complexes Chemistry - A European Journal, 26(48):10992-11006.
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Dynamic dimer–monomer equilibrium in a cycloruthenated complex of [Re(η6-C6H6)2]+ Chemical Communications, 56(73):10658-10661.
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Synthesis and reactivity of the rhenium fulvene sandwich complex [Re(η6-C5H4CH2)(η6-C6H6)]+ Organometallics, 39(14):2713-2718.
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Single crystal growth of water-soluble metal complexes with the help of the nano-crystallization method Dalton Transactions, 49(28):9632-9640.
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Shedding Light on the Molecular Surface Assembly at the Nanoscale Level: Dynamics of a Re(I) Carbonyl Photosensitizer with a Coadsorbed Cobalt Tetrapyridyl Water Reduction Catalyst on ZrO2 Journal of Physical Chemistry C, 124(23):12502-12511.
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2 Catalysis Science & Technology, 10(8):2549-2560.
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Crystal structure of hexacarbonyl-(μ2-methanoato-k2O:O′)-(μ2–bis(di-p-tolylphosphino)cyclohexylamine-κ2P:P′)dirhenium(I), C42H45NO8P2Re2 Zeitschrift für Kristallographie - New Crystal Structures, 235(2):303-305.
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To Sandwich Technetium: Highly Functionalized Bis‐Arene Complexes [99mTc(η6‐arene)2]+ Directly from Water and [99mTcO4]− Angewandte Chemie Internationale Edition, 59(3):1197-1200.
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