Publications
Publications Prof. Roger Alberto 1985 - 2016
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Publications
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Journal Article
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2025
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The role of $\left[\text{Re}(\eta^6\text{-arene})_2\right]^+$ substituents in electro- and photocatalytic water reduction with $\left[\text{Co}(\text{terpy})_2\right]^{3+}$ catalysts Catalysis Science & Technology, 15, 1627–1633. https://doi.org/10.1039/d4cy01282h
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2024
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Synthesis, Characterization, and Biological Evaluation of Novel [M(η6-arene)2]+ (M = Re, 99mTc) Hosted Terpyridines and Copper Complexes Thereof Inorganic Chemistry, 63, 18154–18161. https://doi.org/10.1021/acs.inorgchem.4c03018
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Direct Anchoring of Molybdenum Sulfide Molecular Catalysts on Antimony Selenide Photocathodes for Solar Hydrogen Production ACS Energy Letters, 9, 3828–3834. https://doi.org/10.1021/acsenergylett.4c01570
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Reactivities of Some Unsaturated Hydrocarbons with the Half-Sandwich Complex [Re(η6-C6H6)(NCCH3)3]+ Organometallics, 43, 557–563. https://doi.org/10.1021/acs.organomet.3c00513
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Synthesis and Photophysical Evaluation of 3,3’‐Nitrogen Bis‐Substituted $fac$‐[Re(CO)$_3$(Diimine)Br] Complexes Helvetica Chimica Acta, 107, e202300239. https://doi.org/10.1002/hlca.202300239
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Induced $fac-mer$ rearrangements in {M(CO)$_3$}$^{+}$ complexes (M = Re, $^{99(m)}$Tc) by a PNP ligand Dalton Transactions, 53, 1434–1438. https://doi.org/10.1039/d3dt03992g
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Light-Driven Ring Slippage in [Re(η7-C7H7)(η5-C7H9)]+ and the Inertness of Its Technetium Homologue Inorganic Chemistry, 63, 2701–2708. https://doi.org/10.1021/acs.inorgchem.3c04052
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2023
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From carbonyls to $π$-aromatic arenes: A thirty years journey through organometallic technetium chemistry Journal of Organometallic Chemistry, 1000, 122828. https://doi.org/10.1016/j.jorganchem.2023.122828
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Spectroscopic, X-ray crystallographic and preliminary biological screening study of unsymmetrical diphosphinoamine (PNP’) and monodentate aminophosphine (PNH) ligands coordinated to Pt(II) Inorganica Chimica Acta, 557, 121656. https://doi.org/10.1016/j.ica.2023.121656
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In vivo and in vitro studies of [M(η$^6$-pseudoerlotinib)$_2$]$^+$ sandwich complexes (M = Re, 99m$_T$$_c$) Dalton Transactions, 52, 15757–15766. https://doi.org/10.1039/d3dt03011c
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Binding Small Molecules to a cis-Dicarbonyl $^{\text{99}}$$Tc^{\text{I}}$-PNP Complex via Metal–Ligand Cooperativity Inorganic Chemistry, 62, 10727–10735. https://doi.org/10.1021/acs.inorgchem.3c01177
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Role of Pure Technetium Chemistry: Are There Still Links to Applications in Imaging? ACS Applied Bio Materials, 62, 20539–20548. https://doi.org/10.1021/acs.inorgchem.3c01620
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Reactivities of [Re(η6-C6H6)(η6-C10H8)]+ and [Re(η6-C10H8)2]+ with Cyclic, Nonaromatic Polyenes ACS Applied Bio Materials, 42, 838–845. https://doi.org/10.1021/acs.organomet.3c00136
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Exploring Rhenium Arene Piano-Stool Chemistry with [Re(η6-C6H6)(NCCH3)3]+: A Powerful Semi-Solvated Precursor Inorganic Chemistry, 62, 4227–4237. https://doi.org/10.1021/acs.inorgchem.2c04346
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2022
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One Electron Changes Everything: Synthesis, Characterization, and Reactivity Studies of [Re(NCCH3)6]3+ Inorganic Chemistry, 61, 18325–18334. https://doi.org/10.1021/acs.inorgchem.2c02056
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High-Yield 99mTc Labeling of Gold Nanoparticles Carrying Atropine and Adrenaline Bioconjugate Chemistry, 33, 1741–1749. https://doi.org/10.1021/acs.bioconjchem.2c00351
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Two Novel Dinuclear Cobalt Polypyridyl Complexes in Electro- and Photocatalysis for Hydrogen Production: Cooperativity Increases Performance ChemSusChem, 15, e202201049. https://doi.org/10.1002/cssc.202201049
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Complexes of orotic acid and derivatives with the fac-[M(CO)3]+ (M = Re and 99Tc/99mTc) core as radiopharmaceutical probes Inorganica Chimica Acta, 539, 121037. https://doi.org/10.1016/j.ica.2022.121037
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A Multi-Functional Tool - Cyclopentadienyl Re and 99mTc Complex Synthesis on Highly Functionalised Arenes Journal of Organometallic Chemistry, 962, 122281. https://doi.org/10.1016/j.jorganchem.2022.122281
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Polar Substituents Enable Efficient Catalysis for a Class of Cobalt Polypyridyl Hydrogen Evolving Catalysts Helvetica Chimica Acta, 105, e202100237. https://doi.org/10.1002/hlca.202100237
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Watching Hydrogens Migrate: Step by Step from [ReI(η6-C6H6)2]+ to [ReIII(η3-C6H9)(η6-C6H6)(NCCH3)2]2+ Inorganic Chemistry, 61, 3683–3689. https://doi.org/10.1021/acs.inorgchem.1c03811
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Naphthalene Exchange in [Re(η6-napht)2]+ with Pharmaceuticals Leads to Highly Functionalized Sandwich Complexes [M(η6-pharm)2]+ (M=Re/99mTc) Chemistry, 28, e202103566. https://doi.org/10.1002/chem.202103566
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An isoindoline bridged [M(η6-arene)2]+ (M = Re, 99mTc) ansa-arenophane and its dinuclear macrocycles with axial chirality Dalton Transactions, 51, 9591–9595. https://doi.org/10.1039/d2dt00743f
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2021
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Efficient Alkaline Water Oxidation with a Regenerable Nickel Pseudo-Complex ACS Applied Materials & Interfaces, 13, 48661–48668. https://doi.org/10.1021/acsami.1c13609
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The crystal structure of cis-diaqua-bis (N-butyl-N-(pyridin-2-yl)pyridin-2-amine-κ2N,N′)cobalt(II)] dichloride trihydrate, C28H44Cl2N6O5Co Zeitschrift Für Kristallographie - New Crystal Structures, 236, 1065–1068. https://doi.org/10.1515/ncrs-2021-0221
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Relativity as a Synthesis Design Principle: A Comparative Study of [3 + 2] Cycloaddition of Technetium(VII) and Rhenium(VII) Trioxo Complexes with Olefins Inorganic Chemistry, 60, 11090–11097. https://doi.org/10.1021/acs.inorgchem.1c00995
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Expanding the Cyclopentadienyl Framework: 99mTc/Re Complexes with Orthogonal Functions for Bioconjugation Bioconjugate Chemistry, 32, 1393–1398. https://doi.org/10.1021/acs.bioconjchem.0c00468
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[Re(η6-C6H5-benzimidazole)2]+ and Derivatives as Dye Mimics; Synthesis, UV Absorption Studies and DFT Calculations European Journal of Inorganic Chemistry, 2021, 2493–2498. https://doi.org/10.1002/ejic.202100294
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cis-Locked Ru(II)-DMSO Precursors for the Microwave-Assisted Synthesis of Bis-Heteroleptic Polypyridyl Compounds Inorganic Chemistry, 60, 7180–7195. https://doi.org/10.1021/acs.inorgchem.1c00240
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Exploring the Coordination Chemistry of N2 with Technetium PNP Pincer-Type Complexes Inorganic Chemistry, 60, 6696–6701. https://doi.org/10.1021/acs.inorgchem.1c00503
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Convenient Cyclopentadiene Modifications for Building Versatile (Radio‐)Metal Cyclopentadienyl Frameworks European Journal of Inorganic Chemistry, 2021, 1611–1614. https://doi.org/10.1002/ejic.202100163
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Cobalt Complexes of Polypyridyl Ligands for the Photocatalytic Hydrogen Evolution Reaction Chimia, 75, 180. https://doi.org/10.2533/chimia.2021.180
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Probing BRD Inhibition Substituent Effects in Bulky Analogues of (+)‐JQ1 Helvetica Chimica Acta, 104, e2000214. https://doi.org/10.1002/hlca.202000214
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A novel benzoylthiourea derivative with a triazinethione moiety: Synthesis and coordination with the organometallic fac-[Re(CO)3]+ core Inorganica Chimica Acta, 516, 120116. https://doi.org/10.1016/j.ica.2020.120116
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Excited-state structure of copper phenanthroline-based photosensitizers Physical Chemistry Chemical Physics (PCCP), 23, 26729–26736. https://doi.org/10.1039/d1cp02823e
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Exploring preliminary structural relationships and mitochondrial targeting of fac-[MI(CO)3]-bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re) New Journal of Chemistry, 45, 22141–22149. https://doi.org/10.1039/d1nj04273d
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Organometallic small molecule kinase inhibitors – direct incorporation of Re and 99mTc into Opaganib® Chemical Communications, 57, 13349–13352. https://doi.org/10.1039/d1cc03678e
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New approach for the synthesis of water soluble fac-[MI(CO)3]+ bis(diarylphosphino)alkylamine complexes (M = 99Tc, Re) Dalton Transactions, 50, 17506–17514. https://doi.org/10.1039/d1dt03234h
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2020
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Bioorganometallic Technetium and Rhenium Chemistry: Fundamentals for Applications Chimia, 74, 953. https://doi.org/10.2533/chimia.2020.953
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Fully Solvated, Monomeric ReII Complexes: Insights into the Chemistry of [Re(NCCH3)6]2+ Inorganic Chemistry, 59, 17600–17607. https://doi.org/10.1021/acs.inorgchem.0c02819
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The “Carbonyl Story” and Beyond; Experiences, Lessons and Implications Chembiochem, 21, 2743–2749. https://doi.org/10.1002/cbic.202000387
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CO2 to CO: Photo‐ and electrocatalytic conversion based on Re(I) Bis‐Arene Frameworks: synergisms between catalytic subunits Helvetica Chimica Acta, 103, e2000147. https://doi.org/10.1002/hlca.202000147
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Light‐activated carbon monoxide prodrugs based on bipyridyl dicarbonyl ruthenium(II) complexes Chemistry, 26, 10992–11006. https://doi.org/10.1002/chem.202002139
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Dynamic dimer–monomer equilibrium in a cycloruthenated complex of [Re(η6-C6H6)2]+ Chemical Communications, 56, 10658–10661. https://doi.org/10.1039/d0cc04180g
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Synthesis and reactivity of the rhenium fulvene sandwich complex [Re(η6-C5H4CH2)(η6-C6H6)]+ Organometallics, 39, 2713–2718. https://doi.org/10.1021/acs.organomet.0c00313
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Single crystal growth of water-soluble metal complexes with the help of the nano-crystallization method Dalton Transactions, 49, 9632–9640. https://doi.org/10.1039/d0dt01236j
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Shedding Light on the Molecular Surface Assembly at the Nanoscale Level: Dynamics of a Re(I) Carbonyl Photosensitizer with a Coadsorbed Cobalt Tetrapyridyl Water Reduction Catalyst on ZrO2 Journal of Physical Chemistry C, 124, 12502–12511. https://doi.org/10.1021/acs.jpcc.0c02556
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Mechanistic insights into photocatalysis and over two days of stable H2 generation in electrocatalysis by a molecular cobalt catalyst immobilized on TiO2 Catalysis Science & Technology, 10, 2549–2560. https://doi.org/10.1039/d0cy00330a
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Crystal structure of hexacarbonyl-(μ2-methanoato-k2O:O′)-(μ2–bis(di-p-tolylphosphino)cyclohexylamine-κ2P:P′)dirhenium(I), C42H45NO8P2Re2 Zeitschrift Für Kristallographie - New Crystal Structures, 235, 303–305. https://doi.org/10.1515/ncrs-2019-0632
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To Sandwich Technetium: Highly Functionalized Bis‐Arene Complexes [99mTc(η6‐arene)2]+ Directly from Water and [99mTcO4]− Angewandte Chemie Internationale Edition, 59, 1197–1200. https://doi.org/10.1002/anie.201912994
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